Inter national J our nal of Electrical and Computer Engineering (IJECE) V ol. 8, No. 2, April 2018, pp. 900 907 ISSN: 2088-8708 900       I ns t it u t e  o f  A d v a nce d  Eng ine e r i ng  a nd  S cie nce   w     w     w       i                       l       c       m     Simulation and Modeling of Silicon Based Single Electr on T ransistor Malik Ashter Mehdy , Mariagrazia Graziano, and Gianluca Piccinini Department of Electronics and T elecommunications, Politecnico di T orino, Italy Article Inf o Article history: Recei v ed: Jul 29, 2017 Re vised: Dec 29, 2017 Accepted: Jan 27, 2018 K eyw ord: Single Electron T ransistor TCAD Simulations NEGF Coulomb Blockade T ransmission Spectrum ABSTRA CT In this w ork, we simulated and modeled silicon quantum dot based single electron transistor (SET). W e simulated the de vice using non-equilibrium Green’ s function (NEGF) formal- ism in transport direction coupled with Schrodinger equation in transv erse directions. The characteristics of SET such as Coulomb blockade and Coulomb diamonds were observ ed. W e also present a ne w ef ficient model to calculate the current v oltage ( IV) characteristics of the SET . The IV characteristic achie v ed from the model are v ery similar to those from simulations both in shape and magnitude. The proposed model is capable of reproducing the Coul omb diamond diagr am in good agreement with the simulati ons. The model, which is based on transmission spectrum, is simple, ef ficient and pro vides insights on the ph ysics of the de vice. The transmission spectrum at equilibrium is achie v ed from simulations and gi v en as input to the model. The model then calculates the e v olv ed transmission spectra at non-equilibrium conditions and e v aluates the current using Landauers formula. Copyright c 2018 Institute of Advanced Engineering and Science . All rights r eserved. Corresponding A uthor: Malik Ashter Mehdy Department of Electronics and T elecommunications Politecnico di T orino, corso Duca de gli Abruzzi, 24, T orino, Italy malik.mehdy@polito.it 1. INTR ODUCTION The CMOS technology is at the v er ge of the miniaturization and it needs to be replaced by the ne w tech- nologies which should o v ercome its limitations. One of the most promising technologies is the one based on single electron tunneling phenomenon. If a metallic or semiconducting is land is placed between the electrodes separated by the tunnel junctions wi th v ery small capacitance, the single electron phenomenon can be observ ed. When an electron tunnels into the island it raises t he electrostatic potential of island stopping the tunneling of the follo wing electrons until e xternal potential is applied. This phenomenon is also kno wn as Coulomb blockade. If the island size is v ery small (so that the capacitance is v ery small), tunneling of single electrons can be controlled by the e xternal electrode potentials. Hence the de vices based on single electron phenomenon ha v e the attrib utes of small size and lo w po wer consumption. Ov er the years, man y dif ferent schemes for digital logic using single electron transistor ha v e been presented [1–5]. In one scheme, the l ogic states are represe n t ed by the single electrons located at tin y metallic electrodes [1]. While such a scheme can pro vide the huge benefits in terms of high speed and v ery lo w po wer consumption, its practical implementation f aces serious challenges. Firstly , the y should be operated at temperature much less than the critical temperature, otherwise a thermally induced tunneling e v ent can change the entire calculation. Secondly , the output of one logic g ate (single electron) should be capable of char ging the input of follo wing g ates. This requires the stray capacitance of interconnections to be k ept ne gligible and complicated design rules for dif ferent number of subsequent g ates [2]. The de vices based on silicon are v ery important part of the today’ s digital w orld [6–8]. Single electron transistors (SET) based on silicon ha v e been pre viously studied in [9–11]. In order to operate the transistor at room temperature, the size of the is land should be less than 5nm [12]. The nano-lithograph y techniques no w a days allo w to define such small structures with only a fe w v ariations. In this w ork, we simulate and model the SET based on J ournal Homepage: http://iaescor e .com/journals/inde x.php/IJECE       I ns t it u t e  o f  A d v a nce d  Eng ine e r i ng  a nd  S cie nce   w     w     w       i                       l       c       m     DOI:  10.11591/ijece.v8i2.pp900-907 Evaluation Warning : The document was created with Spire.PDF for Python.
IJECE ISSN: 2088-8708 901 a ) H e i g h t W i d t h L e n g t h b ) C o n t a c t C o n t a c t Si l i con Insulator Ai r Si  Island T unnel Junction T unnel Junction Figure 1. a) The three-dimensional structure of the de vice which is simulated in Atlas TCAD b) Cross section of the same de vice as seen from the sides. Dif ferent materials and the dimensional parameters are highlighted and drain and source contacts are mentioned. The g ate contact is all around the de vice. silicon quantum dot with a size of 1nm. W e present tw o no v el contrib utions in this w ork. i) W e simulate Si based SET , for the first time, using Atlas TCAD [13] with non-equilibrium Green’ s function (NEGF) technique. The results are comparable to the e xperimental results with similar de vice s. NEGF formalism is a rob ust technique for the quantum le v el simulations. Anantram et. al used NEGF technique to model nanode vices [14]. The transport through quantum dot weakly coupled with the contacts is studied using NEGF technique in [15]. ii) W e propose transmission spectrum based model for the e v aluation of SET characteristics. The proposed model, which is the e xtended v ersion of [16], uses transmission spectrum to calculate the current. It does not need an y comple x initial set up and is v ery ef ficient, simple, suf ficiently accurate and fle xible to implement in dif ferent conditions. In comparison, Monte Carlo based models [17] are accurate b ut v ery time consuming. Macromodel ing based models [18] [19] are ef ficient b ut pro vide a little ph ysical insights on the de vice beha vior . Analyt ical models based on ph ysics [20] and master e qu a tion [21] solv e this problem b ut the y still require a comple x procedure to calculate tunnel junction resistances and capacitances [22]. These models require the tunnel junction resistances and capacitances as input while the proposed model requires transmission spectrum as input. The transmission spectrum pro vides insights on the ph ysics of de vice especially about the density of states of island which lacks in case of other models. W e can easily change the model for the v ariations in contact coupling, g ate coupling and density of state v ari ations due to dif ferent f abricated size of island. From the transmission spectrum current is calculated usi n g Landauers formula. The rest of the paper is or g anized as follo ws . In section II the e xplanation of t h e de vice and simulations are described. In section III the details of proposed model are gi v en. In section IV the results are discussed and the section V concludes the paper . 2. RESEARCH METHODOLOGY W e simulated the single electron transistor (SET) based on silicon island and the drain and source contacts made of highly doped silicon (Fig. 1). The cross section of the island (height into width) is 1x1nm and the length is 2nm. The tunnel junctions are created by the g ap between the island and contacts. These g aps pro vide the confinement in the transport direction and decouple the island from electrodes. The silicon island is w arped by the oxide through which g ate contact controls the conduction in the island. The de vice w orks as the single e lectron transistor and sho ws the characteristics of SET such as Coulomb diamonds as sho wn in results section. W e simulated the de vice in Atlas TCAD using non-equilibrium Green’ s function (NEGF) formalism i n transport direction coupled with Schrodinger equation in transv erse direction. The simulator uses mode space technique instead of solving 2d or 3d problem. First solving the Schrodinger equat ion eigen v alues and eigen v ectors are calculated in each slice of de vice. Then a transport equation is solv ed for electrons mo ving in lo west sub-bands which are occupied. This reduces the size of the problem [13]. But still the simulations are v ery time consuming and there is a need for an ef ficient model. From the simulations, we can achie v e the transmission spectrum (TS) at equilibrium which i s fed to the model to compute the IV characteristics. The IV characteristics are also calculated from the simulations to compare with those from the model. Simulation and Modeling of Silicon Based Single ... (Malik Ashter Mehdy) Evaluation Warning : The document was created with Spire.PDF for Python.
902 ISSN: 2088-8708 Figure 2. The flo w chart of the model: at equilibrium, the transmission spectrum is constructed using parameters from simulations, while at non-equilibrium conditions, shift is calculated by the self-consistent loop. 3. THE PR OPOSED MODEL The propose d model uses transmission spectrum (TS) to calculate the characteristics of single electron tran- sistors. In our pre vious w orks, we ha v e implemented earlier v ersions of t he model to molecular de vices [23] and silicon nanocrystals [16]. The current model is implemented on SET and the dif ference from [23] is the implemen- tation of tw o spectra for dif ferent spin as e xplained in [16]. In this w ork, we e xtend the model presented in [16] to implement the g ate v oltage in order to use the silicon nanocrystal as SET . Further e xplanation on the modeling of g ate v oltage can be found in the follo wing description and in the results section. The model tak es as input the transmission spectrum at equilibrium from the simulations. From the transmission spectrum, current i s calculated using Landauers formula. The e v olution in transmission spectrum with applied v oltage is calculated by the model using self-consistent field technique. By e v aluati n g the TS at all v oltages ( V ds ; V g ) and using the Landauers formula, IV characteristics of the de vice can be calculated [24]. W e calculate the TS at equilibrium using Atlas TCAD. The TS parameters i.e. position, amplit ud e and width of peaks are gi v en as input to the model. The model uses these parameters to construct the TS at equilibrium. The shape of the peaks is defined by the Lorentzian function. D 0 = k 0 N or m ( 1 2 ( E ) 2 + 2 ) (1) Here D 0 is the transmission peak defined o v er the range of ener gies E , is the position of the corresponding peak and is the sum of drain and source rate constants 1 , 2 . The width (or broadening) of the transmission peaks is defined by . After normalizing the Lorentzian function, it is multiplied by the amplit ud e of the corresponding peak k 0 . Other peaks are calculated similarly and then TS is constructed by adding all the transmission peaks. The same procedure is repeated for both spins and tw o spectra are achie v ed. Although at this point both the spectra are similar , the dif ference arises when the shift in spectra is calculated as e xplained belo w . When the v oltage is applied, transmission spectrum shifts on the ener gy axis. The shift is caused by the e xternal potential and because of the change in number of electrons. At equilibrium, the Fermi le v el of island is IJECE V ol. 8, No. 2, April 2018: 900 907 Evaluation Warning : The document was created with Spire.PDF for Python.
IJECE ISSN: 2088-8708 903 aligned with the drain and source chemical potential. When the drain to source v oltage ( V ds ) is applied the drain and source chemical potential split and the separation is so called bias windo w . If there is a transmis sion peak inside or at the edge of the bias windo w then the number of electrons ( N ) at the island change. If the transmission peak corresponds to the spin up electrons the change in number of electrons are calculated using follo wing formula. N U P =D N = 1 f 1 U P =D N ( ) + 2 f 2 U P =D N ( ) 1 + 2 (2) Here f 1 U P =D N ( ) and f 2 U P =D N ( ) are the drain and source Fermi functions with respect to the corresponding spin up/do wn transmiss ion peaks ( ) If the number of electrons increase in the island the ener gy of the system increases so the transmission spectrum shifts to w ards higher ener gies and vice v ersa. The o v erall shift is the result of both i.e. change in number of electrons and the applied drain to source bias. The po s iti v e g ate v oltage lo wers the ener gy of the island so it shifts the transmission spectrum to w ards lo w ener gies. The o v erall shift ( U ) can be calculated using: U U P =D N = U L + U 0 N D N =U P (3) where U 0 is the single electron char ging ener gy , N D N =U P is the change in number of spin do wn/up electrons and U L = d V ds + g V g is Laplace potential. The ef fect of the e xternal v oltages is modeled by the coupling coef ficients d ; g . Equation 2 and 3 are solv ed self-consistently to calculate the shift in tra nsmission spectrum with respect to the applied v oltage. The shift in both the spectra for spin up and spin do wn is calculated. The shift in the spin up transmission spectrum is calculated from t he change in number of spin do wn electrons as spin up electron feels the potential due to spin do wn electron and vice v ersa [24]. When a posi ti v e g ate v oltage is applied and a lo west unoccupied molecular le v el (LUMO) goes bel o w the drain and source chemical potentials, the number of electrons increase on the island. This increase in number of electrons causes the rate constant ( ) to decrease so the width of the transmission peaks also reduces. In the current v ersion of the model, the change in width is calculated using fitting parameters. Another ef fect of the increase in number of electrons on the island is to reduce the g ate coupling ( g ). W ith the increase in number of electrons on the island the amount of shift in transmission spectra due to increase in g ate v oltage reduces. W e implement this -2 -1 0 1 2 3 Energy (eV) 0 1 2 3 Model Si mul ations -2 -1 0 1 2 3 0 1 2 3 Model Si mul ations (b) -2 -1 0 1 2 3 Energy (eV) 0 1 2 3 Model Si mul ations -2 -1 0 1 2 3 Ener gy (eV) 0 1 2 3 Model Si mul ations T r anmissi on -2 -1 0 1 2 3 Energy (eV) 0 1 2 3 Model Si mul ations (a) (d) (c) E f =0 HOMO-LU MO Gap (e) Figure 3. T ransmission spectra at dif ferent V g and V ds achie v ed from simulations and model. The bias windo w is sho wn as the dashed lines. a) V g = 0 : 0 V , V ds = 0 : 0 V b) V g = 1 : 0 V , V ds = 0 : 0 V c) V g = 1 : 0 V , V ds = 1 : 0 V d) V g = 1 : 5 V , V ds = 1 : 0 V e) V g = 2 : 5 V , V ds = 1 : 0 V . Simulation and Modeling of Silicon Based Single ... (Malik Ashter Mehdy) Evaluation Warning : The document was created with Spire.PDF for Python.
904 ISSN: 2088-8708 ef fect in the model by linear fitting of g with respect to the change in number of electrons ( N ) . After e v aluating the transmission spectra e v olv ed with the applied v oltage we can find the current using Landauers formula. I U P =D N = q 2 h Z + 1 1 T U P =D N ( E )[ f 1 ( E ) f 2 ( E )] dE (4) Here q is the electron char ge, h is plank’ s constant and T ( E ) is the transmission spectrum. The dif ference between the source and drain Fermi functions models the ef fect of bias windo w so that only the part of transmission spectrum which is inside the bias windo w is inte grated. The total current is calculated by the sum of spin up and spin do wn currents. 4. RESUL TS AND DISCUSSION Single electron transistor based on silicon quantum dot of 1nm cross section w as simulated in Atlas TCAD using NEGF formalism coupled with Schrodinger equation. The IV characteristics of the de vice were calculated from simulations as well as from the model. In Fig. 3 the transmission spec tra (TS) from simulati ons and model are sho wn for dif ferent v alues of V g and V ds . The lo west unoccupied molecular le v els (LUMO) are sho wn while the highest occupied molecular le v els (HOMO) are not sho wn because the y do not contrib ute to the conduction in this case as the y are f ar belo w the Fermi ener gy le v el ( E f = 0 ). The HOMO-LUMO g ap and the Fermi ener gy le v el are also mentioned in the Fig. 3 (a). The LUMO le v els are relati v ely closer to Fermi le v el and by applying a positi v e g ate v oltage we can shift them near Fermi le v el (Fig. 3 (b)). Then at a small v alue of V ds LUMO1 enters inside the bias windo w and contrib utes to current (Fig. 3 (c,d,e)). The comparison between the IV characteristics is sho wn in the Fig. 4. Drain current is plotted as a function of drain to source bias for dif ferent v alues of g ate v oltage. At lo w g ate v oltages (i.e. less than 1 V) there are no transmission peaks inside the bias windo w s o a v ery small current flo ws through de vice because of tunneling of electrons with v ery lo w probability . The model pro vides acceptable estimation of the current as sho wn in the figure in case of V g = 0 : 7 ; 0 : 8 ; 0 : 9 ; 1 : 0 V . The first peak starts to enter in the bias windo w at V g = 1 V as sho wn in the Fig. 3 (c). 0.8V 1.2V 1.6V 0.7V 1.4V 2.1V 1.1V 1.3V 1.5V 1.0V 1.7V 2.3V (a) (b) (c) (d) 2.4V 0.9V Figure 4. Comparison of IV characteristics of the de vice at v arious g ate v oltages between the model and simulations. Dif ferent cur v es are for dif ferent g ate v oltages mentioned by the curv es. At lo wer g ate v olt ages, less than 1.0V , there are no peaks inside the bias windo w . First peak enters in the bias windo w at V g = 1 : 1 V so a high current flo ws. As the g ate v oltage increases other peaks also contrib ute to the current. IJECE V ol. 8, No. 2, April 2018: 900 907 Evaluation Warning : The document was created with Spire.PDF for Python.
IJECE ISSN: 2088-8708 905 -1 -0.5 0 0.5 1 Drain to Source Voltage(V) -20 -10 0 10 20 Drain Current( µ A) Simulations Model Vg=1.8V 0 0.5 1 Drain to Source Voltage(V) 0 10 20 30 40 50 Drain Current( A) Simulations Model w/o Spin Model w Spin Figure 5. a) IV characteristics of the simulated de vice at g ate v oltage equal to 1.8V and for both positi v e and ne g ati v e drain to source bias. b) IV characteristics obtained from the pre vious model without considering the spin and from the current model with the dif ferent spectra for spin at V g = 2 : 0 V . The current is modeled v ery ef fecti v ely at the g ate v oltages higher than 1V (Fig. 4) because the bias windo w , for the selected range of V ds , includes the transmission peaks. As the model is transmission spectrum based so the results are better when there is a transmission peak inside the bias windo w . F or the sak e of clarity , the dif ferent curv es sho wn here are selected in such a w ay that the y do not o v erlap each other . In Fig. 5 (a) the IV characteristics for both positi v e and ne g ati v e drain to source bias are sho wn for V g = 2 : 0 V . This sho ws that our model is v alid for bidirectional electron flo w . And in the Fig. 5 (b) the results from the pre vious model without considering the spin (a) (b) (c) Figure 6. The current plotted as a funct ion of V ds and V g . The shade of gre yscale represents the drain current v alue based on the scale sho wn in the figure. The three figures are obtained from a) simulations b) model c) model using refined set of applied v oltages. Simulation and Modeling of Silicon Based Single ... (Malik Ashter Mehdy) Evaluation Warning : The document was created with Spire.PDF for Python.
906 ISSN: 2088-8708 of electron (Model w/o Spin) is compared with the proposed model (Model w Spin) under the same conditions and parameters. W e can see that the proposed model pro vides v ery accurate results compared t o the pre vious v ersion of the model in [23]. The current as a function of V ds and V g is plotted on grayscale in Fig. 6. The magnitude of the current is represented by the shade of the gray according to the scale sho wn in the figure. The dark re gions represent the zero or v ery small current while t he current of higher magnitudes is represented by the light re gions. The coulomb blockade diamonds which are unique characteristics of SET can be seen i n the form of dark re gions. One lar ge blockade diamond and one small one can be observ ed in the figure. The model successfully predicts the same beha vior as obtained from simulations. The resolution of the plots in Fig. 6 (a,b) is not good and it w ould tak e high computational ef fort to increase it in case of simulations. W e ha v e sho wn the high resolution achie v ed from the model in Fig. 6 (c). The time required for t he calculations in Fig. 6 (a,b) is 6346s by the TCAD simulations and 1.57s by the model. The model tak es 128s for the calculation with high resolution plot (210 V ds points and 260 V g points) Fig. 6 (c). All the simulations were performed on the same system with the Intel core i5 1.8 GHz processor and 6 GB of RAM. The proposed model pro vides suf ficiently accurate results while maintaining the ef ficie nc y . While other compact models based on macromodeling are also ef ficient, the proposed model captures the ph ysical information of de vic e with more details. 5. CONCLUSIONS In this w ork, we simulated and modeled the single electron transistor based on silicon quantum dot. W e simulated the de vice in Atlas TCAD using NEGF formalism in t ransport direction coupled with Schrodinger equation in transv erse direction. The SET characteristics such as Coulomb blockade and Coulomb diamonds were observ ed in the results obtained from the simulations and the model. The IV characteristics of the SET were obtained from the model ha ving a good agreement with the simulations. The proposed model is simple, ef ficient, fle xible and pro vides insights on the ph ysics of the de vice. In the future, we will include in the model the ef fect of the change in number of electrons on the width of the transmission peaks. W e will also use the de vice for circuit le v el implementation. REFERENCES [1] K. Likhare v , “Single-electron transistors: Electrostatic analogs of the DC SQ UIDS, IEEE tr ansactions on ma g- netics , v ol. 23, no. 2, pp. 1142–1145, 1987. [2] J. 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IJECE ISSN: 2088-8708 907 [14] M. Anantram et al. , “Modeling of nanoscale de vices, Pr oceedings of the IEEE , v ol. 96, no. 9, pp. 1511–1550, 2008. [15] N. A. Zimbo vskaya, “Electron transport through a quantum dot in the Coulomb blockade re gime: nonequilibrium Green’ s function based model, Physical Re vie w B , v ol. 78, no. 3, p. 035331, 2008. [16] M. A. Mehdy et al. , An ef ficient model for e v aluating current in silicon nanocrystals, in Ph. D. Resear c h in Micr oelectr onics and Electr onics (PRIME), 2016 12th Confer ence on . IEEE, 2016, pp. 1–4. [17] C. W asshuber et al. , “SIMON-A simulator for single-electron tunnel de vices and circuits, IEEE T r ansactions on Computer -Aided Design of Inte gr ated Cir cuits and Systems , v ol. 16, no. 9, pp. 937–944, 1997. [18] Y . S. Y u et al. , “Macromodeling of single-electron transistors for ef ficient circuit simulation, IEEE tr ansactions on electr on de vices , v ol. 46, no. 8, pp. 1667–1671, 1999. [19] A. Ghosh et al. , “A modified macro model approach for SPICE based simulation of single electron transistor, J ournal of Computational Electr onics , v ol. 15, no. 2, pp. 400–406, 2016. [20] S.-H. Lee et al. , “A practical SPICE model based on the ph ysics and characteristics of realistic single-electron transistors, IEEE tr ansactions on nanotec hnolo gy , v ol. 99, no. 4, pp. 226–232, 2002. [21] K. Miyaji et al. , “Compact analyti cal model for room-temperature-operating silicon single-electron transistors with discrete quantum ener gy le v els, IEEE tr ansactions on Nanotec hnolo gy , v ol. 5, no. 3, pp. 167–173, 2006. [22] S. Mahapatra et al. , “Analytical modeling of single electron transistor for h ybrid CMOS-SET analog IC design, IEEE T r ansactions on Electr on De vices , v ol. 51, no. 11, pp. 1772–1782, 2004. [23] A. Zahir et al. , “EE-BESD: molecular FET modeling for ef ficient and ef fecti v e nanocomputing design, J ournal of Computational Electr onics , v ol. 15, no. 2, pp. 479–491, 2016. [24] S. Datta, Quantum tr ansport: atom to tr ansistor . Cambridge Uni v ersity Press, 2005. BIOGRAPHIES OF A UTHORS Malik Ashter Mehdy recie v ed his B.E. Electronics de gree from Federal Urdu Uni v ersi ty , Islam- abad, P akistan in 2011 and M.S. de gree in Nanote chnology from Politecnico di T orino, Italy in 2014. He is currently a PhD student in Department of Electronics and T elecommunication at Po- litecnico di T orino,Italy . His research interests include, simulation and modeling of silicon based single electron transistor . Mariagrazia Graziano recei v ed the DrEng and the PhD de grees in Electronics Engineering from the Politecnico di T orino, Italy , in 1997 and 2001, respecti v ely . Since 2002, she is a researcher and since 2005, an assistant professor at the Politecnico di T orino. Since 2008, she is adjunct f aculty at the Uni v ersity of Illinois at Chicago and since 2014 she is a Marie-Skodo wska-Curie Intra-European Fello w at the London Centre for Nanotechnology . Her re search interests include design of CMOS and be yond CMOS de vices, ci rcuits and architectures. She is author and coauthor of more than 120 published w orks. She is a Member of the IEEE since 2007. Further info on her homepage: http://www .det.polito.it/personale/scheda/(nominati v o)/mariagrazia.graziano Gianluca Piccinini is a Full Professor since 2006 at the Department of Electronics of Po- litecnico di T orino, Italy , where he teaches electron de vices and inte grated system technol- ogy . He recei v ed the Dr . Ing and the Ph.D. de grees in electronics engineering in 1986 and 1990 respecti v ely . His research acti vities started at the end of the 1980s, were initially fo- cused on VLSI architecture for artificial intelligence and mo v ed, during the 1990s, to w ard the ph ysical design of VLSI systems for high rat e and high-speed transmission and coding algo- rithms. His current interests in v olv e the introduction of ne w technologies as molecular elec- tronics in inte grated systems where he studies transport, adv anced microf abrication and self- assembly technologies in molecular scale systems. He is author and co-author of more than 100 published w orks and is the holder of one international patent. Further info on his homepage: http://www .det.polito.it/personale/scheda/(nominati v o)/gianluca.piccinini Simulation and Modeling of Silicon Based Single ... (Malik Ashter Mehdy) Evaluation Warning : The document was created with Spire.PDF for Python.